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The forbidden gap between the conduction band and the valence band is maximum for ________.

Asked in GUJCET 2020 · Energy bands and band gap

Answer: (2) Insulator

Step-by-step solution

Idea: the forbidden gap E_g is the energy an electron must gain to cross from the valence band into the conduction band, and its size is what separates the three classes of solid.

Metal: the two bands overlap, so E_g is effectively zero and electrons are free at any temperature.

Semiconductor: E_g is small, near 1 eV, so thermal energy frees a small number of carriers.

Insulator: E_g is large, several eV and about 6 eV in diamond, so practically no electron crosses and no current flows.

The forbidden gap is therefore largest for the insulator.

Why the other options are wrong

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