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At constant volume temperature is increased, then

Asked in NEET 1989 · Origin of pressure and wall impacts

Answer: (2) number of collisions per unit time will increase

Step-by-step solution

Idea: at fixed volume the number of molecules and the space they move in are unchanged, so only their speed responds to the temperature.

vᵣₘₛ=√(3RT)/M, so raising T raises the mean speed.

The mean free path λ=1/(√2 nπ d²) depends on the number density alone, which has not changed.

Collision rate =(mean speed)/(mean free path), with a faster numerator and the same denominator.

So the number of collisions per unit time increases.

Why the other options are wrong

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