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Some energy levels of a molecule are shown in the figure with their wavelengths of transitions. Then:

Asked in Re-NEET 2024 · Energy levels and ionisation

Figure: Energy levels and ionisation
Answer: (4) λ₂>λ₁, λ₂=2λ₃

Step-by-step solution

λ=(hc)/(Δ E).

λ₁: -5/2E→-4E, Δ E=3/2E. λ₂: -2E→-3E, Δ E=E. λ₃: -2E→-4E, Δ E=2E.

(λ₂)/(λ₃)=(2E)/E=2, so λ₂=2λ₃.

(λ₁)/(λ₂)=E/(3E/2)=2/3, so λ₂>λ₁.

Why the other options are wrong

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