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Given below are two statements: Statement-I : The contact angle between a solid and a liquid is a property of the material of the solid and liquid as well. Statement-II : The rise of a liquid in a capillary tube does not depend on the inner radius of the tube. In the light of the above statements, choose the correct answer from the options given below:

Asked in JEE Main 4th April 2nd Shift 2024 · Concept and assertion

Answer: (2) Statement-I is true but Statement-II is false.

Step-by-step solution

Statement-I: at the contact line the three interfacial tensions T_sg, Tₛₗ and T_lg balance, and cos θ=(T_sg-Tₛₗ)/(T_lg).

All three depend on which solid and which liquid are in contact, so θ is a property of the pair. Statement-I is true.

Statement-II: balancing the weight of the raised column against the vertical pull of the surface film gives h=(2T cos θ)/(ρ gr).

The radius r sits in the denominator, so the rise certainly does depend on it. Statement-II is false.

Statement-I true, Statement-II false.

Why the other options are wrong

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