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Which statements are correct about degrees of freedom? (A) A molecule with n degrees of freedom has n² different ways of storing energy. (B) Each degree of freedom is associated with 1/2 RT average energy per mole. (C) A monoatomic gas molecule has 1 rotational degree of freedom whereas a diatomic molecule has 2 rotational degrees of freedom. (D) CH₄ has a total of 6 degrees of freedom.

Asked in JEE Main 27th July 2nd Shift 2022 · Degrees of freedom and equipartition

Answer: (2) (B) and (D) only

Step-by-step solution

(A) n degrees of freedom give n ways of storing energy, not n². False.

(B) Equipartition assigns 1/2 RT per mole to each degree of freedom. True.

(C) A monoatomic molecule has no rotational degrees of freedom at all, not one. False.

(D) CH₄ has 3 translational and 3 rotational degrees of freedom, so 6 in total. True.

The correct pair is (B) and (D).

Why the other options are wrong

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